#RobSelects paper of the week #angew_chem: Probing electrostatic interactions in nucleophilic substitutions through rotation rates in molecular motors with analogous structures. #physorg https://doi.org/10.1002/anie.202505483
#RobSelects paper of the week #angew_chem: Probing electrostatic interactions in nucleophilic substitutions through rotation rates in molecular motors with analogous structures. #physorg https://doi.org/10.1002/anie.202505483
#RobSelects paper of the week #J_A_C_S: Quantifying halogenophilic and chalcogenophilic nucleophilic substitution rates. #physorg https://doi.org/10.1021/jacs.4c12463
#RobSelects preprint of the week #ChemRxiv: Measuring the nucleophilicity of water and alcohols under vibrational strong coupling reveals no substantial differences to classical conditions. #physorg https://doi.org/10.26434/chemrxiv-2024-q81sk
#RobSelects paper of the week #J_A_C_S: Isolating and characterizing a chiral persistent aminyl diradical with a triplet ground state. #physorg https://doi.org/10.1021/jacs.4c02057
#RobSelects paper of the week #J_A_C_S: Constraining water to act as a chalcogen bond acceptor inside a molecular cage. #physorg https://doi.org/10.1021/jacs.3c13604
#RobSelects paper of the week #ChemicalScience: In-depth investigation of fluoride transfer from tetra-n-butylammonium difluorotriphenylsilicate via NMR spectroscopy. #physorg https://doi.org/10.1039/D3SC05776C
#RobSelects paper of the week #ChemSci: Design of molecules showing reduced charge recombination rates of photogenerated charge-separated states upon temperature increase. #physorg https://doi.org/10.1039/D3SC03609J
#RobSelects paper of the week #J_A_C_S: Evaluating the magnitude of hole upconversion in electron hole-catalyzed Diels-Alder reactions to establish thermodynamic guidelines. #physorg https://doi.org/10.1021/jacs.3c06106
#RobSelects paper of the week #J_A_C_S: Influence of vibrational strong coupling on the solvatochromic response of Reichardt's dye in alcoholic solvents. #physorg https://doi.org/10.1021/jacs.3c02260
#RobSelects paper of the week #J_A_C_S: Making ionic bonds directional with a nonpolar shield. #physorg https://doi.org/10.1021/jacs.3c01030